Titanium, like aluminium, is found in relatively abundant quantities in the lithosphere and in soils, but is poorly absorbed and retained by plants
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Login4.1.2. Soils and sediments
Though titanium is ubiquitous in its geographical distribution, regional levels vary considerably according to conditions such as weathering, fallout from consumption of fossil fuels, and incineration of refuse. Sandy soils, e.g., sand, bog, loess, and calcareous soils contain less titanium than heavy clay soils.
According to an extensive review by Vinogradov (1959) of titanium values in soils from various parts of the world ..., the average concentration in soil appears to be below 5 g/kg. However, some soils contain titanium dioxide at a concentration of about 10-100 g/kg.
Grabarov (1970) found that the titanium content of soils in Kazakhstan, USSR, ranged from 2 to 7 g/kg but that only 10-50 mg/kg was in a readily soluble form. Hussain & Islam (1971) measured titanium in soil, silt, and clay fractions of a number of soils from the Barind tract in Bangladesh. The mean titanium dioxide content in the soils ranged from 6 to 12 g/kg with an average value of 8 g/kg. The content in the clay fraction was higher than that in the silt fraction, with these soils showing signs of the development of argillic horizons.
Soils in the vicinity of power and incineration plants and industrial discharges may be enriched in heavy metals and trace elements. Klein & Russel (1973) reported that soils around a coal- burning power plant contained higher levels of trace metals than surrounding areas. The average level of titanium in soils in the vicinity of this power plant was 92 mg/kg compared with a back- ground level of 56 mg/kg. The enriched area covered 300 km2 with the enrichment confined to the upper 2 cm of soil.
Nearly all exposures to titanium are to dusts, though some exposure to fume and vapour occurs in handling titanium tetrachloride. Occupational exposure to titanium mainly occurs in the mining and production of the metal, and in the production and processing of titanium dioxide and carbide. During the extraction and recovery of titanium from its major ores such as ilmenite and rutile, the atmospheric concentrations of the ores may reach levels commonly regarded as the maximum permissible for inert or nuisance dusts.
In the preparation of raw materials, i.e., crushing, grinding, mixing, and sieving of rutile concentrates and technical grade titanium dioxide - the concentration of dust depends on the humidity of the air and on the materials treated. According to Kokorev et al. (1960), the dust concentration in the air of crushing rooms, containers, and transporters, amounted to 4- 6 mg/m3. Considerable concentrations of titanium tetrachloride vapour were found in the chlorine department.
In some other departments, such as the crushing and classification departments, the concentration of titanium dust (titanium-rich slag containing about 70% titanium dioxide) may reach 30-50 mg/m3.
Exposure to titanium and its compounds occurs not only in the production of metallic titanium, but also in processes in which it is used. According to Mezenceva et al. (1963), in the production of hard alloys, the dust concentration in the air during the sieving of titanium carbide ranged from 20.3 to 40.2 mg/m3, while in the process of carbonization, it amounted to 22 mg/m3.
Skurko & Brahnova (1973) reported high concentrations of titanium dust in the breathing zone of workers employed in the manufacture of titanium hydride. High mean concentrations up to 500 mg/m3 were found in the hydrogenation shop, manual handling, screening, and packaging of the powder. Cleaning of the retort resulted in a mean concentration of 210 mg/m3.